Solvation of a Small Metal-Binding Peptide in Room-Temperature Ionic Liquids
نویسندگان
چکیده
منابع مشابه
Room Temperature Ionic Liquids
The initial objective of this project was to carry out a fundamental study of the transport characteristics of a variety of gases and organic solutes in room temperature ionic liquids. The goal was to combine information collected from a number of different experimental measurements in order to develop a fundamental understanding of the interactions governing transport in ionic liquids. Measure...
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Effect of two room temperature ionic liquids (RTIL, [pmim][Br] and [pmim][BF4]) on the solvation dynamics and anisotropy decay of coumarin 480 (C480) in P123 gel has been studied using femtosecond up-conversion. In P123 gel, C480 displays a significant excitation wavelength dependence of emission maximum (red edge excitation shift, REES of 18 nm) and solvation dynamics, which suggest heterogene...
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Room temperature ionic liquids (RTILs) are comprised of bulky organic cations and anions (Holbrey & Seddon, 1999; Weingärtner, 2008). Because of the intricate interplay of various interand intramolecular interactions, RTILs have rich dynamical properties and have found diverse applications. In particular, negligible vapor pressure of RTILs makes them a green alternative of conventional organic ...
متن کاملSolvation dynamics in room temperature ionic liquids: Dynamic Stokes shift studies of fluorescence of dipolar molecules
Room temperature ionic liquids (RTILs) have attracted tremendous interest in recent years as promising media, which could be an alternative to the environmentpolluting, volatile common organic solvents. In this article, we focus on the studies of dynamic Stokes shift of the fluorescence spectra of dipolar solutes in RTILs. These studies throw light on the nature of solvation dynamics in media t...
متن کاملElectrochemical Applications of Room - Temperature Ionic Liquids
R3 R2 There is good evidence that the first room-temperature ionic liquid or RTIL was identified and characterized by Walden in 1914, who examined the electrical conductivity of ethylammonium nitrate.1 Thus, it would not be an exaggeration to say that the very beginnings of electrochemistry involved room-temperature ionic liquids! Although once considered to be a curious subset of the general c...
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ژورنال
عنوان ژورنال: Bulletin of the Korean Chemical Society
سال: 2012
ISSN: 0253-2964
DOI: 10.5012/bkcs.2012.33.11.3601